Before you bring down Xplosives, kill all the outlaws in the area. The most important are the snipers at the top of the valley. Just shoot the explosive barrels with zapflies to get 'em. Next, kill the two outlaws on the ledges by shooting the explosive barrels in the openings. Take out the gatling gun wielding outlaws next with boombats or whatever. Finally, kill the stragglers. Shoot the three switches to bring Xplosives down to your level when he approaches in his cart. A big ass machine gun lowers to help him out, so take it out with some boombats. To capture Xplosives alive, shoot a combination of thudslugs and charged zapflies at him to lower his stamina. If you keep it at a steady pace, he won't be able to get up. Bounty him up once he's drained.
This is out of memory, so it might not be the best approach.
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