"Further back, in the Stone Age, people made solid cakes from
stone-crushed barley and wheat. A millstone used for grinding corn
has been found, that is thought to be 7,500 years old."
"Grown in Mesopotamia and Egypt, wheat was likely first merely chewed. Later it was discovered that it could be pulverized and made into a paste. Set over a fire, the paste hardened into a flat bread that kept for several days. It did not take much of a leap to discover leavened (raised) bread when yeast was accidentally introduced to the paste.
Weak i know, but it was the best that came up on a search of History of Bread
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