You can also get MGS2:Substance for PC.
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MGS1 for PC has troubles running fine on newer systems, and it's stripped of some features. And you get things like "Press Select Button" on keyboard
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Really? I don't use my copy for a couple of years, but I thought it was working. Also, there's a lot of patches to make it playable. That could be a pain in the ass, getting all patches and fixes for your computer...