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I imagine we'll perhaps have the ability to drill down beyond the crust of a planet by the time we have the technology to terraform. So maybe we can just clusterfuck the core with like, ten Tsar Bomba sized nukes? Hurpa durp.
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That would probably only blow the planet apart. Molten cores occur because of the mass of the planet and the pressure pushing down on them.
In any case, Mars's core is molten. It's just that the crust has solidified to the point that it's no longer moving about.