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I know you and Nikki are big fans of Eureka Seven, which was more awesome than I could have expected.
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That's the only one I can think of off the top of my head. I've watched Hell Girl on and off, but I can't account for how recent that is.
Also, I think FLCL counts as early 00's. I know sure as hell it wasn't dubbed until then. That's another one of my favorites.
Blue Submarine No. 6 was another great one in the same vein. I prefer quality of animation/story over quantity of episodes. Dragon Ball was the one exception, but it also had enough filler that I could miss an episode on occasion and still be on the same page.