:
The usless items stay usless
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Not all of them, though. For example, the Ghoul who wants Sugar Bombs and two people who want Scrap Metal, and both of those are pretty much useless.
Do the Enclave guys drop advanced power armour? Because I already got three sets of normal power armour (albeit damaged) from
those metal knight dudes on the way to Galaxy News Radio.
As for Deathclaws - I remember in Fallout 2 there was one you could save from
a laboratory in some Enclave outpost place, and after you did that you could go to the Deathclaw cave and
they wouldn't attack you. In fact, I believe they gave you a
G.E.C.K., unless that was some other cave.
I already have a Fat Man, a Flamer and a Missile Launcher, too, which are pretty damn powerful (though I haven't actually used any of them yet). If there's something better than the Fat Man, I'd love to see it

.