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MEGATRON.
Because "Puny Flesh Creatures!" Is all you need to say.
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Oh, come now. Megatron isn't ALL-OVER hateable, though I do hate some of his antics he does with his lackeys (and how he treated Starscream, now there I hated him for that)
Hmm...I can't recall some villains I've loved to hate on. The guards in Oblivion, not totally villains, but I love to hate on them. XD